Catalyst transfer polycondensation
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Name (Latin)
Catalyst transfer polycondensation
Other forms of name
Catalyst transfer polymerization
CTP (Catalyst transfer polycondensation)
Transfer polycondensation, Catalyst
Transfer polymerization, Catalyst
See Also From tracing topical name
Polycondensation
MARC
MARC
Other Identifiers
Wikidata:
Q49000047
Library of congress:
sh2020006014
Sources of Information
- Work cat.: Buenaflor, J. Designing nickel- and palladium-based precatalysts to improve catalyst-transfer polymerization towards conjugated polymer synthesis, 2019:abstr. (Catalyst transfer polymerization (CTP) is a versatile synthetic tool to obtain access to sequence specific [pi]-conjugated polymers, which are attractive materials for organic electronics. CTP proceeds through a chain-growth mechanism creating polymers with precise molecular weights, narrow dispersities, and end-group functionalization)
- Wikipedia, June 25, 2020(Catalyst transfer polymerization (CTP), or Catalyst transfer polycondensation, is a type of living chain-growth polymerization that is used for synthesizing conjugated polymers)
- Nature communications, v. 9(1):3866 (2018):p. 1 (article title: Identifying the missing link in catalyst transfer polymerization; abstr.: Nickel-catalyzed catalyst transfer polycondensation (CTP) of thiophenes is an efficient strategy for the controlled synthesis of polythiophene) p. 2 (Among current strategies for polythiophene synthesis, nickel-catalyzed catalyst transfer polycondensation (CTP) has proven particularly effective in the production of polythiophenes with high-molecular weights, regioregularity, low polydispersities, and end-group control)
- Coordination chemistry reviews, v. 376 (Dec. 1, 2018):p. 225 (Catalyst-transfer polymerization has enabled synthesizing conjugated polymers with unmatched control over both polymer sequence and end-group identity) p. 226 (catalyst-transfer polymerization (CTP), is effective for polymerizing a range of (hetero)aromatic monomers, with the best results obtained for electron-rich substrates)
- Macromolecules, v. 46(21) (12 Nov. 2013):p. 8395 (Conjugated polymer synthesis via catalyst-transfer polycondensation (CTP); a living, controlled chain-growth method for synthesizing [pi]-conjugated polymers)
- Smith, M.L. Expanding the utility of catalyst-transfer polymerization, 2017:p. xvi (Conjugated polymers are electronically tunable semiconductors that can be solution-processed onto flexible substrates, making them valuable materials for electronic devices including bulk-heterojunction (BHJ) solar cells. Historical syntheses of [pi]-conjugated polymers have been step-growth; however, the development of catalyst-transfer polymerization (CTP) has led to precise control over molecular weight, dispersity, and copolymer sequence) p. 6 (each catalyst remains associated with a single polymer chain throughout the polymerization. This mechanism has been termed catalyst-transfer polymerization (CTP))
- Chemical science, v. 10 (2019):p. 2075 (Catalyst transfer polycondensation is the only method to prepare [pi]-conjugated polymers in a chain-growth manner)
- Google search, June 25, 2020(7,620 results for "catalyst transfer polymerization"; 11,600 results for "catalyst transfer polycondensation")
Wikipedia description:
Catalyst transfer polymerization (CTP), or catalyst transfer polycondensation, is a type of living chain-growth polymerization that is used for synthesizing conjugated polymers. Benefits to using CTP over other methods are low polydispersity and control over number average molecular weight in the resulting polymers. Very few monomers have been demonstrated to undergo CTP.
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